化学学报 ›› 2008, Vol. 66 ›› Issue (18): 2065-2069. 上一篇    下一篇

研究论文

N,N’-二(2-吡啶基)-1,6,7,12-四(4-叔丁基苯氧基)-3,4:9,10-苝酰亚胺的合成、表征及性能研究

王洪宇 彭 波 韦 玮*

  

  1. (复旦大学光科学与工程系 先进光子学材料与器件国家重点实验室 上海 200433)
  • 收稿日期:2008-03-09 修回日期:2008-05-08 出版日期:2008-09-28 发布日期:2008-09-28
  • 通讯作者: 韦 玮

Synthesis, Characterization and Properties of N,N’-Bi(2-pyridyl)-1,6,7,12-terta(4-tert-butylphenoxy)-perylene- 3,4:9,10-tetracarboxylic Diimide

WANG, Hong-Yu PENG, Bo WEI, Wei*   

  1. (State Key Laboratory for Advanced Photonic Materials & Devices, Department of Optical Science and Engineering,
    Fudan University, Shanghai 200433)
  • Received:2008-03-09 Revised:2008-05-08 Online:2008-09-28 Published:2008-09-28
  • Contact: WEI, Wei

优化了N,N’-二(2-吡啶基)-1,6,7,12-四(4-叔丁基苯氧基)-3,4:9,10-苝酰亚胺的合成方法, 得到一种简单有效的在苝酰亚胺的酰胺和bay位置同时取代的方法. 对其结构进行了表征, 研究了其溶液态和薄膜态的光学性质和电化学性质. 并且对其能级结构和电荷分布进行了分子模拟.

关键词: 苝酰亚胺, 合成, 光电特性, 分子模拟

The synthetic methods of N,N’-bi(2-pyridyl)-1,6,7,12-terta(4-tert-butylphenoxy)-perylene-3,4: 9,10-tetracarboxylic diimide were optimized. A simple and effective synthetic method to substitute at both imide and bay positions was gained. The structure was investigated. And its optical and electrochemical properties were studied in both solution and thin films. And the theoretical calculations were also carried out regarding the energy levels and electron distribution.

Key words: perylene diimide, synthesis, optoelectronic property, molecular simulation