On-surface chemical reactions under ultra-high vacuum play an important role in the synthesis of two-dimensional nanomaterials and have attracted more and more attention in recent years. In this review, we introduce several typical organic on-surface chemical reactions, including organic-metal coordinated reaction, dehalogenation reaction, condensation polymerization, alkyne coupling and so on. Reaction process and products are analyzed in detail by scanning tunneling microscope (STM), especially for the connection way of final products after reaction, such as organic metal coordination bonds, C-C bonds and H-bonds.
郝振亮,阮子林,杨孝天,蔡逸婷,卢建臣,蔡金明. 超高真空环境下有机分子表面化学反应的研究进展[J]. 化学学报, 0, (): 0-0.
Hao Zhenliang, Ruan Zilin, Yang Xiaotian, Cai Yiting, Lu Jianchen, Cai Jinming. Research Progress of on-surface Chemical Reaction for Organics in Ultra-High Vacuum. Acta Chim. Sinica, 0, (): 0-0.