Acta Chimica Sinica ›› 2012, Vol. 70 ›› Issue (06): 707-713.DOI: 10.6023/A1107222 Previous Articles     Next Articles

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1-乙基-3-甲基咪唑磷酸二甲酯盐+K3PO4/K2HPO4/K2CO3+H2O 离子液体双水相体系在T=298.15 K 时相图数据的测量和相关性

王良a,b, 朱红a,b, 闫永胜c   

  1. a 吉林师范大学化学学院 四平 136000;
    b 环境友好材料制备与应用省部共建教育部重点实验室 四平 136000;
    c 江苏大学化学化工学院 镇江 212013
  • 投稿日期:2011-07-22 修回日期:2011-12-02 发布日期:2011-12-12
  • 通讯作者: 闫永胜

Measurement and Correlation of the Phase Diagram Data for 1-Ethyl-3-methylimidazolium Dimethyl phosphate+K3PO4/ K2HPO4/K2CO3+H2O lonic Liquids Aqueous Two-Phase Systems at T=298.15 K

Wang Lianga,b, Zhu Honga,b, Yan Yongshengc   

  1. a Department of Chemistry, Jilin Normal University, Siping 136000;
    b Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, Ministry of Education, Siping 136000;
    c Department of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013
  • Received:2011-07-22 Revised:2011-12-02 Published:2011-12-12

Binodal data for the 1-ethyl-3-methylimidazolium dimethyl phosphate ([Emim]DMP)+salt (K3PO4, K2HPO4, and K2CO3)+H2O systems were experimentally determined at 298.15 K. Three empirical equations were used to correlate binodal data. The Merchuk equation is an uncomplicated one for fine accuracy. The ability of different salts studied for phase separation are in the order of K3PO4>K2HPO4>K2CO3, which may be related to the Gibbs free energy of hydration of the ions (ΔhydG). The reliability of the calculation method and the corresponding tie-line data was described by the Othmer-Tobias equation and Bancroft equation, as well as the two-parameter equation. [Emim]DMP is a familiar ionic liquid, which is extensively used for extractive desulfurization of fuel oils. This is the first time to report the data for phase diagrams of [Emim]DMP+salt+water systems.

Key words: phase diagram data, [Emim]DMP, K3PO4/K2HPO4/K2CO3, ionic liquids aqueous two-phase systems