Recent Progress of Li4Ti5O12 with Different Morphologies as Anode Material

doi:10.6023/A13040423

Abstract

Lithium-ion battery has developed rapidly in the past decades due to growing needs of electronic and information industries. Nowadays, the demand for lithium-ion batteries is still increasing and safety requirements are higher and higher. Therefore, exploration of a new anode material that is high safety and excellent cycle ability, as compared to commercial carbon/graphite materials, has been extensively attempted to meet the new need such as electric vehicles industry. Spinel Li₄Ti₅O₁₂ as an anode material of power lithium-ion battery has become a research hotspot due to its appealing features such as "zero-strain" structure characteristic, excellent cycle stability, low cost, simple synthesis, high safety feature and flat charge-discharge voltage plateau (1.55 V vs. Li/Li⁺). It is also considered as one of the most promising anode material for lithium-ion battery. Despite many advantages associated with Li₄Ti₅O₁₂, it can not meet the need of large-scale applications due to its pretty low electric conductivity (10^-13 S·cm^-1), moderate Li⁺ diffusion coefficient (10^-9～10^-13 cm²·s^-1) and theoretical capacity (175 mAh·g^-1). Several methods have been utilized to improve the conductivity and energy density of Li₄Ti₅O₁₂, such as synthesis of nano-sized particle, ion doping, doping Li₄Ti₅O₁₂ with other metals or metal oxides, coating Li₄Ti₅O₁₂ with conductive carbons, nitridation on Li₄Ti₅O₁₂ surface and composite anode materials prepared by Li₄Ti₅O₁₂ and other anodes. In addition, unique structure has been proved as an effective way to improve the electric conductivity of the material. Moreover, morphology has also an important effect on electrochemical performances of Li₄Ti₅O₁₂ such as specific capacity, specific energy, specific power, high rate performance and cycle life. This review focuses on the present status of different morphologies Li₄Ti₅O₁₂ including spherical structure, porous (hollow) structure, nano-micro structure, core-shell structure, one-dimensional, two-dimensional and three-dimensional nanostructures, then summarized their advantages, resolved and unresolved problems, common synthesis methods and application areas, respectively. At last, the future development prospects of Li₄Ti₅O₁₂ are presented.

Key words: Li₄Ti₅O₁₂, morphology, progress, anode material, lithium-ion battery

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Zhang Yonglong, Hu Xuebu, Xu Yunlan, Ding Mingliang. Recent Progress of Li₄Ti₅O₁₂ with Different Morphologies as Anode Material[J]. Acta Chimica Sinica, 2013, 71(10): 1341-1353.

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不同形貌结构Li₄Ti₅O₁₂负极材料的最新进展

Recent Progress of Li₄Ti₅O₁₂ with Different Morphologies as Anode Material

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不同形貌结构Li4Ti5O12负极材料的最新进展