Acta Chim. Sinica ›› 2017, Vol. 75 ›› Issue (1): 34-40.DOI: 10.6023/A16090491 Previous Articles     Next Articles

Special Issue: 有机光化学

Review

可见光催化的交叉偶联放氢反应

钟建基, 孟庆元, 陈彬, 佟振合, 吴骊珠   

  1. 中国科学院理化技术研究所 光化学转换与功能材料重点实验室 北京 100190
  • 收稿日期:2016-09-14 修回日期:2016-11-13 出版日期:2017-01-15 发布日期:2016-11-24
  • 通讯作者: 吴骊珠,E-mail:lzwu@mail.ipc.ac.cn E-mail:lzwu@mail.ipc.ac.cn
  • 作者简介:钟建基,2015年毕业于中国科学院理化技术研究所,获理学博士学位;孟庆元,2013年毕业于中国科学院理化技术研究所,获得博士学位;张宝文,研究员;2007年毕业于中国科学院理化技术研究所,获理学博士学位,师从佟振合院士.目前在中国科学院理化技术研究所超分子光化学研究中心工作,任项目研究员,硕士生导师,主要从事超分子体系中的光物理和光化学研究;佟振合,1963年毕业于中国科技大学,1983年毕业于美国哥伦比亚大学,获博士学位.1999年被选为中国科学院院士.现为中国科学院理化技术研究所研究员、博士生导师.主要从事物理有机化学和有机光化学研究;吴骊珠,1995年毕业于中国科学院感光化学研究所,获理学博士学位.
  • 基金资助:

    项目受自然科学基金委(Grant Nos.21390404,91427303,21402217),科技部(Grant Nos.2013CB834804,2013CB834505,2014CB239402),中国科学院战略性先导科技专项(B类)(No.XDB17030200)资助.

Visible Light Induced Cross-Coupling Hydrogen Evolution Reactions

Zhong Jian-Ji, Meng Qing-Yuan, Chen Bin, Tung Chen-Ho, Wu Li-Zhu   

  1. Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190
  • Received:2016-09-14 Revised:2016-11-13 Online:2017-01-15 Published:2016-11-24
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Grant Nos. 21390404, 91427303, 21402217), the Ministry of Science and Technology of China (Grant Nos. 2013CB834804, 2013CB834505, 2014CB239402), the Strategic Priority Research Program of the Chinese Academy of Sciences (No. XDB17030200).

Taking advantages of the mild, clean and earth-abundant characters of visible light catalysis, we have invented a new reaction, namely cross-coupling hydrogen evolution (CCHE) reaction, for the construction of a series of C-C bond, C-X (heteroatom) bond, or X-X bond directly from two different C-H bonds, C-H and X-H bonds, or X-H and X-H bonds, respectively. In contrast to traditional strategies, this CCHE reaction avoids the use of any external oxidant and H2 is the sole product at ambient condition. In this contribution, we will highlight the development of CCHE reaction since the first report in 2013 to provide guidance for cleaner, safer, and more efficient, step-economic and atom-economic organic transformation.

Key words: cross-coupling hydrogen evolution, visible light catalysis, environmentally friendly, atom-economy, synthetic strategy