Acta Chimica Sinica ›› 1953, Vol. 19 ›› Issue (2): 77-85.
Pang Chang1, Lythgoe Cambridge2
The anhydro ring in a-methyl 2:3-anhydro-4:6-benzylidene-D-allopyranoside has been opened by the action of sodium benzylate to give 53% yield of a-methyl 2-benzyl-4:6-benzylidene-D-altropyranoside and 9% of a-methyl 3-benzyl-Q:6-benzylidene-D-glucopyranoside. After the removal of the benzylidene residue by acid hydrolysis, the position of attaclunent of the benzyl group is determined by periodate oxidation.
Pang Chang, Lythgoe Cambridge. A Study of the Scission of Ethylene Oxide Ring in α-Methyl 2：3-Anhydro-4：6-benzylidene-D-allopyranoside by Sodium Benzylate[J]. Acta Chimica Sinica, 1953, 19(2): 77-85.
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