Acta Chimica Sinica ›› 1959, Vol. 25 ›› Issue (6): 411-416. Previous Articles     Next Articles

有机磷化合物的研究Ⅴ. O,O-二烷基三硫代过氧磷酸硝苯基酯的合成

胡秉方, 陈万义   

  1. 北京农业大学
  • 收稿日期:1958-08-25 出版日期:1959-12-15 发布日期:2013-06-03

RESEARCHES ON ORGANO-PHOSPHORUS COMPOUNDS——Ⅴ.THE SYNTHESIS OF O,O-DIALKYLNITROPHENYLTRITHIOPEROXYPHOSPHATES

HU PING-FANG, CHEN WAN-YI   

  1. Peking Agricultural University
  • Received:1958-08-25 Online:1959-12-15 Published:2013-06-03

Several O,O-dialkylnitrophenyltrithioperoxyphosphates are synthesized according to the following chemical equation.

It has been found that the reaction proceed,smoothly with yieeds up to 90%.In spite of the structural similarity of these compounds with E-605, all of these coma pounds, with the exception of O,O-diethyl 4-nitrophenyltrithioperoxyphosphate, exhibit extremely feeble insecticial activities.The O,O-dialkyl nitrophenyltrithioperoxyphosphates are stable at room temperature in solid state, but at elevated temperature or in refluxing ethyl alcohol, they decompose exclusively into nitrophenyldisulfides and othet products.