Acta Chimica Sinica ›› 1963, Vol. 29 ›› Issue (4): 236-242.
張志炳, 李成宗, 謝仙德
CHANG CHIH-BING, LEE CHENG-CHUNG, SHIEH SHIAN-DEH
1.The stationary potentials of zinc electrode in potassium hydroxide solutions (feom 0.2 N to saturated solution) have been measured.When the concentration of potassium hydroxide is greater than 1 N, the φc～logαKOH plot shows a linear relation, the slope of which is found to be -59 mv.2.The anodic polarization curves of zinc electrode in potassium hydroxide solutions (from 1.07 N to 8.31 N) were measured, the linear portions of which have a slope of 40 mv.It has been found that at constant current densities, when the logαKOH changes by one unit, the anodic potential shifts about 80 mv.
CHANG CHIH-BING, LEE CHENG-CHUNG, SHIEH SHIAN-DEH. ELECTROCHEMICAL MECHANISM OF ANODIC DISSOLUTION AND SELF-DISSOLUTION OF ZINC IN POTASSIUM HYDROXIDE SOLUTIONS[J]. Acta Chimica Sinica, 1963, 29(4): 236-242.
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