Acta Chimica Sinica ›› 1965, Vol. 31 ›› Issue (3): 229-235. Previous Articles     Next Articles

悬汞电极的研究——Ⅲ.静止球面电极恒电位伏安法扩散电流方程式的验证

高鴻, 張長庚   

  1. 南京大学化学系
  • 收稿日期:1964-07-24 出版日期:1965-06-15 发布日期:2013-06-03

INVESTIGATIONS ON HANGING MERCURY ELECTRODE Ⅲ. EXPERIMENTAL VERIFICATION OF THE THEORY OF SYMMETRICAL SPHERICAL DIFFUSION AT VARIOUS POTENTIALS

KAO HUNG, CHANG CH'ANG-GENG   

  1. Department of Chemistry, Nanking University
  • Received:1964-07-24 Online:1965-06-15 Published:2013-06-03

The instantaneous current obtained on hanging mercury electrode in voltammetry with constant potential obeys the following equation

for electrode reaction in which both the oxidized and reduced forms are soluble in solution.