Acta Chimica Sinica ›› 1965, Vol. 31 ›› Issue (3): 236-245. Previous Articles     Next Articles

不饱和碳氢化合物的水化反应——Ⅰ.三甲基乙烯在强酸溶液中的水化速度及反应机理

刘雲浦, 王正烈, 侯得顯   

  1. 天津大学化工系物理化学教研室
  • 收稿日期:1964-09-18 出版日期:1965-06-15 发布日期:2013-06-03

THE HYDRATION OF UNSATURATED HYDROCARBONS Ⅰ. THE HYDRATION RATE OF TRIMETHYLETHYLENE AND ITS REACTION MECHANISM IN AQUEOUS SOLUTIONS OF STRONG ACIDS

LIU YUN-PU, WANG CHENG-LIEH, HOU TEH-HSIEN   

  1. Department of Chemical Engineering, Tientsin University
  • Received:1964-09-18 Online:1965-06-15 Published:2013-06-03

The hydration rate of trimethylethylene is investigated in a wider range of hydrochloric (0.1-2.6 M),perchloric (0.1-2.5 M),and sulphuric (0.25-2.5 M) acid solutions.At constant acid strength,the rate is strictly of the first order with respect to the concentration of the olefin,while it increases rapidly with the increase of the acid concentration.