Acta Chimica Sinica ›› 1980, Vol. 38 ›› Issue (2): 175-184.
陈庆云, 马振中, 蒋锡夔, 张元发, 贾世茂
CHEN QING-YUN, MA ZHEN-ZHONG, JIANG XI-KUI, ZHANG YUAN-FA, JIA SHI-MAO
Vinylidene fluoride has been successfully telomerized with carbon tetrachloride and perfluoro-t-butyl iodide as telogens; various new telomerization products and new compounds derived. therefrom have been identified by NMR, IR, elemental analyses and chemical transformations. In agreement with our view that polar factors play an important part in deciding the orientation of free radical additions to vinylidene fluoride, it has been shown that the electrophilic radicals·CCl3and (CF3) 3C ·add to the methylene end of the alkene.
CHEN QING-YUN, MA ZHEN-ZHONG, JIANG XI-KUI, ZHANG YUAN-FA, JIA SHI-MAO. TELOMERIZATIONS OF VINYLIDENE FLUORIDE WITH PERHALOALKANES AND THE STUDY OF THEIR PRODUCTS[J]. Acta Chimica Sinica, 1980, 38(2): 175-184.
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