Acta Chimica Sinica ›› 1981, Vol. 39 ›› Issue (6): 541-545. Previous Articles     Next Articles

昆虫保幼激素类似物——萜烯基硫醚类化合物的合成

刘孟英, 阎忠诚   

  1. 中国科学院动物研究所 北京
  • 收稿日期:1979-08-28 出版日期:1981-11-15 发布日期:2013-06-03

SYNTHESIS OF JUVENILE HORMONE ANALOGUES——TERPENOID THIOETHERS

LIU MENG-YING, YAN ZHONG-CHENG   

  1. Institute of Zoology, Academia Sinica, Beijing
  • Received:1979-08-28 Online:1981-11-15 Published:2013-06-03

10 new torpenoid thioethers,such as 6,1O-dimethyl 3-thia-undeoa-5,9-dienoio acid esters(8) and 6,1O-dimethyl 9,1O-epoxy-3-thia-6-undeoenoio acid esters(4) were synthesized by condensation of thioglycolio acid esters with geranyl chloride(1) or 6,7-epoaygeranyl chloride(2).Juvenile hormonal activities of the synthotio compounds to pupae of meal worm(Tenebrio molitor L.) were studied.It has been proved that the activities of the epoxy compounds(4) is higher than those of the olefinio compounds(8).Compounds of type 4 showed moderate morphogenetio effect to meal worm pupae at a dosage of 50 μg/pupa.