Acta Chimica Sinica ›› 1989, Vol. 47 ›› Issue (1): 1-5.     Next Articles

Original Articles

[(C2H5)4N]2{Fe4S4[S2CN(C2H5)2]4}的晶体和分子结构

杨光第;孙宏林;徐吉庆;千吉松;魏诠   

  1. 吉林大学理论化学研究所;吉林大学化学系
  • 出版日期:1989-01-15 发布日期:1989-01-15

Crystal and molecular structure of [(C2H5)4N]2{FeS4[S2CN(C2H5)24}

YANG GUANGDI;SUN HONGLIN;XU JIQING;QIAN JISONG;WEI QUAN   

  • Online:1989-01-15 Published:1989-01-15

The title compound belongs to space group Cc with a 22.125(6), b 11.313(3), c 25.053(8) ? and b 118.05(2)? dc = 1.45 for Z = 4. The structure was refined to R = 0.073 and Rw = 0.069 for 1934 reflections. The structure contains Fe4S4 clusters with cubane-like configurations. Each Fe atom in the cluster is coordinated with 5 S atoms which are located on the vertexes of a distorted square pyramid. The atomic parameters are given.

Key words: CRYSTAL STRUCTURE DETERMINATION, TERTIARY AMINE, MOLECULAR STRUCTURE, X-RAY DIFFRACTION ANALYSIS, COMPUTER APPLICATIONS, IRON COMPLEX, NITROGENASE, CLUSTER COMPOUND, DIETHYLAMINE P, SULFIDE COMPLEX

CLC Number: