Acta Chimica Sinica ›› 1989, Vol. 47 ›› Issue (1): 64-66. Previous Articles     Next Articles

Original Articles

钼铁硫原子簇化合物的合成与结构化学IV: 双类立方烷化合物与酰氯的反应

康北笙;吴达旭;刘汉钦   

  1. 中国科学院福建物质结构研究所
  • 出版日期:1989-01-15 发布日期:1989-01-15

Synthesis and structural studies of molybdenum-iron-sulfur compounds IV: Novel reaction of pseudo-dicubane cluster with acyl chloride

KANG BEISHENG;WU DAXU;LIU HANQIN   

  • Online:1989-01-15 Published:1989-01-15

Pseudo-dicubane cluster compound I reacted with AcCl in MeCN to give II with extrusion of Fe(SPh)3 bridge. This novel reaction was characterized by 1H NMR study and elemental anal. of the product.

Key words: IRON COMPLEX, ACYL CHLORIDES, PROTON MAGNETIC RESONANCE SPECTROMETRY, STRUCTURAL ANALYSIS, MOLYBDENUM COMPLEX, CLUSTER COMPOUND, ACETIC ACID P, SULFIDE COMPLEX, CUBANE, BRIDGE COMPOUNDS

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