Acta Chimica Sinica ›› 1991, Vol. 49 ›› Issue (8): 827-832. Previous Articles    

Original Articles

金属锡作用下烯丙基溴与α,β-不饱和醛、酮和醌的反应

高翔;黄邦州;吴世晖   

  1. 复旦大学化学系
  • 出版日期:1991-08-15 发布日期:1991-08-15

Reaction of allyl bromides with α,β-unsaturated aldehydes, ketones and quinones

GAO XIANG;HUANG BANGZHOU;WU SHIHUI   

  • Online:1991-08-15 Published:1991-08-15

In the presence of metallic tin, allyl bromides react with a,b-unsatd. aldehydes and ketones regioselectively to give only 1,2-addn. products. Allylquinones were obtained by the reaction of 1,4-quinones with allyl bromides and metallic tin, followed by oxidation with ferric chloride.

Key words: TIN, BROMIDE, QUINONE, QUINONE, CARBONYL COMPOUNDS, ADDITION REACTION, KETONE, ALLYL GROUP, ALLYL GROUP, UNSATURATED COMPOUND

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