Acta Chimica Sinica ›› 1992, Vol. 50 ›› Issue (8): 767-771. Previous Articles     Next Articles

Original Articles

由蒽镁真空热解合成的活性镁的加氢性能

廖世健;张双青;余淑文   

  1. 中国科学院大连化学物理研究所;中国科学院上海有机化学研究所
  • 出版日期:1992-08-15 发布日期:1992-08-15

Hydrogenation behaviour of active magnesium synthesized by the thermal decomposition of magnesium anthracene in vacuum

LIAO SHIJIAN;ZHANG SHUANGQING;YU SHUWEN   

  • Online:1992-08-15 Published:1992-08-15

The synthesis of active Mg by the thermal decomposition of Mg anthracene in vacuum is a method which does not consume any reagents in principle. This active Mg can be hydrogenated with the formation of MgH2 under normal pressure. The optimum temperature for the hydrogenation reaction is 230? The order of the hydrogenation reaction with respect to the Mg surface area is one. The apparent activation energy is 43 kJ/mol. The reason for the high activity of this Mg is closely related to its high dispersion and its large clean surface. Electron microscopy data reveal that the size of the primary particles of the active Mg belongs to the field of nano-materials.

Key words: MAGNESIUM, HYDROGENATION, THERMOLYSIS

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