Synthesis, structure and properties of [Mn(phen)2(H2O)2]2[HOCH2CH2O].4H2O

Acta Chimica Sinica ›› 1997, Vol. 55 ›› Issue (8): 786-793. Previous Articles Next Articles

Original Articles

[Mn(phen)2(H2O)2]2[Cr(OX)3][HOCH2CH2O].4H2O的合成、晶体结构及性质

牛淑云;杨忠志;郭文生;杨冰;陈亚东;杨光第;张丽芳;徐吉庆;黄小荥

辽宁师范大学化学系;辽宁师范大学结构化学国家重点实验室;吉林大学理论化学研究所;吉林大学结构化学国家重点实验室;中国科学院福建物质结构研究所;中国科学院福建结构化学国家重点实验室

发布日期:1997-08-15

Synthesis, structure and properties of [Mn(phen)2(H2O)2]2[HOCH2CH2O].4H2O

NIU SHUYUN;YANG ZHONGZHI;GUO WENSHENG;YANG BING;CHEN YADONG;YANG GUANGDI;ZHANG LIFANG;XU JIQING;HUANG XIAOXING

Published:1997-08-15

Abstract

The crystal of complex [Mn(phen)2(H2O)2]2[Cr(OX)3][HOCH2CH2O].4H2O have been synthesized. The structure of single crystal was determined by X-ray diffraction. The crystal is monoclinic system, space group P2/c with a=1.0602(3), b=1.3515(3), b=2.1508(3)nm, β=102.57(2)°, V=3.008(1)nm^3, Z=2, Dc=1.49g/cm^3, F(000)=1392, R=0.067, Rw=0.079. The UV-Vis-NIR, IR, XPS and ESR spectra of the complex have been determined and the temperature dependenced of magnetic susceptibility investigated. Based on this, the related properties of the complex have been discussed.

Key words: ULTRAVIOLET SPECTROPHOTOMETRY, INFRARED SPECTROPHOTOMETRY, CRYSTAL STRUCTURE, X-RAY DIFFRACTION ANALYSIS, BENZENE P, POTASSIUM COMPOUNDS, CHROMIUM COMPOUNDS, ELECTRON SPIN RESONANCE, OXALIC ACID P, MANGANESE COMPLEX

CLC Number:

O621

Cite this article

NIU SHUYUN;YANG ZHONGZHI;GUO WENSHENG;YANG BING;CHEN YADONG;YANG GUANGDI;ZHANG LIFANG;XU JIQING;HUANG XIAOXING. Synthesis, structure and properties of [Mn(phen)2(H2O)2]2[HOCH2CH2O].4H2O[J]. Acta Chimica Sinica, 1997, 55(8): 786-793.

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[Mn(phen)2(H2O)2]2[Cr(OX)3][HOCH2CH2O].4H2O的合成、晶体结构及性质

Synthesis, structure and properties of [Mn(phen)2(H2O)2]2[HOCH2CH2O].4H2O

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