Acta Chimica Sinica ›› 1999, Vol. 57 ›› Issue (3): 321-328. Previous Articles     Next Articles

Original Articles

新型氮杂大环化合物的研究2: 四吡唑类卟啉大环化合物的合成 及配位性能

陶京朝;吴养洁;喻正炎;邹大鹏   

  1. 郑州大学化学系.郑州(450052);河南省高校应用化学重点实验室
  • 出版日期:1999-03-15 发布日期:1999-03-15

Studies on the new aza-macrocycles 2: Syntheses and coordinating behaviour of tetrapyrazolic porphyrinogenic macrocycles

Tao Jingchao;Wu Yangjie;Yu Zhengyan;Zou Dapeng   

  1. Zhengzhou Univ, Dept Chem.Zhengzhou(450052)
  • Online:1999-03-15 Published:1999-03-15

We report in this paper the syntheses and complexing behaviour for Ru(II) of four tetrapyrazolic porphyrinogenic macrocycles. Some of the ligands can form stable octahedral complex with Ru(II). Two same or different axial ligands, such as DMSO, CH~3CN or Pyridine, located above and below the complexing plane, respectively, can be easily thermoexchanged.

Key words: NITROGEN HETEROCYCLICS, PYRAZOLE P, PORPHYRIN, RUTHENIUM COMPLEX, COMPLEX REACTION, COORDINATE CHEMISTRY, FOUNDATION OF NATIONAL SCIENCE FOUNDATION COMMITTEE

CLC Number: