Acta Chimica Sinica ›› 2006, Vol. 64 ›› Issue (21): 2205-2209. Previous Articles     Next Articles

Original Articles

含氨基酸单元的手性主体的合成及手性识别研究

徐括喜, 刘顺英, 何永炳*, 秦海娟, 卿光焱, 胡翎   

  1. (武汉大学化学系 武汉 430072)
  • 投稿日期:2006-01-17 修回日期:2006-06-12 发布日期:2006-11-14
  • 通讯作者: 何永炳

Study on Synthesis and Chiral Recognition of Chiral Hosts Containing Amino Acid Unit

XU Kuo-Xi; LIU Shun-Ying; HE Yong-Bing*; QIN Hai-Juan; QING Guang-Yan; HU Ling   

  1. (Department of Chemistry, Wuhan University, Wuhan 430072)
  • Received:2006-01-17 Revised:2006-06-12 Published:2006-11-14
  • Contact: HE Yong-Bing

Two chiral fluorescence hosts (1, 2) based on L-alanine and 2,7-dihydroxynaphthalene were synthesized and their structures were characterized by IR, 1H NMR, 13C NMR, mass spectra and elemental analysis. The chiral recognition property of such hosts was studied by 1H NMR and fluorescence spectra. The results demonstrate that hosts 1 and 2 with bis(tetrabutylammonium) dibenzoyl tartrate formed 1∶1 complexes. The host 1 exhibit a good chiral recognition ability toward the enantiomers of bis(tetrabutylammonium) dibenzoyl tartrate.

Key words: chiral hosts, synthesis, fluorescence sensor, chiral recognition, amino acid derivative