Acta Chimica Sinica ›› 2006, Vol. 64 ›› Issue (22): 2265-2270. Previous Articles     Next Articles

Original Articles


梅芳1, 何锡文1, 李娟1, 李文友*,1, 张玉奎*,1,2   

  1. (1南开大学化学系 天津 300071)
    (2中国科学院大连化学物理研究所 国家色谱研究分析中心 大连 116011)
  • 收稿日期:2005-11-19 修回日期:2006-04-29 出版日期:2006-11-28 发布日期:2006-11-28
  • 通讯作者: 李文友

Influence Factors for the Synthesis of Water-soluble CdSe/CdS Core-shell Nanoparticles and Their Effects on the Spectral Characterization of CdSe/CdS

MEI Fang1; HE Xi-Wen1; LI Juan1; LI Wen-You*,1; ZHANG Yu-Kui*,1,2   

  1. (1 Department of Chemistry, Nankai University, Tianjin 300071)
    (2 National Chromatographic R. & A. Center, Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116011)
  • Received:2005-11-19 Revised:2006-04-29 Online:2006-11-28 Published:2006-11-28
  • Contact: LI Wen-You

CdSe nanoparticles capped by CdS were synthesized in the aqueous solution at room temperature using cysteine (Cys) as the stabilizer. X-ray powder diffraction and transmission electron microscopy were used to analyze the core/shell nanoparticle structure and determine their average size, size distribution and shape. Fluorescence spectra were used to probe the effect of time, pH, quantity of shell, adding rate of shell precursors and the quantity of Cys on the spectral characterization of CdSe/CdS.

Key words: nanoparticle, core/shell structure, CdSe/CdS, cysteine