Acta Chimica Sinica ›› 2006, Vol. 64 ›› Issue (4): 331-337. Previous Articles     Next Articles

Original Articles

meso-四(邻烷氧基苯基)卟啉及其铜配合物的合成、表征和性能研究

赵鸿斌*,罗和安,贺江平,彭圣明,谢琼玉   

  1. (湘潭大学化学化工学院 湘潭 411105)
  • 收稿日期:2005-06-21 修回日期:2005-10-17 出版日期:2006-02-28 发布日期:2006-02-28
  • 通讯作者: 赵鸿斌

Synthesis, Characterization and Properties of meso-Tetrakis(2-alkoxyphenyl)porphyrins and Their Copper(II) Complexes

ZHAO Hong-Bin*, LUO He-An, HE Jiang-Ping, PENG Sheng-Ming, XIE Qiong-Yu*, LUO He-An, HE Jiang-Ping, PENG Sheng-Ming, XIE Qiong-Yu   

  1. (College of Chemistry and Chemical Engineering, Xiangtan University, Xiangtan 411105)
  • Received:2005-06-21 Revised:2005-10-17 Online:2006-02-28 Published:2006-02-28
  • Contact: ZHAO Hong-Bin

A series of meso-tetrakis(2-alkoxyphenyl)porphyrin derivatives [(ROPh)4PH2] and their copper(II) complexes [(ROPh)4PCu] were synthesized, and sixteen of them were new compounds. For the first time, [(ROPh)4PH2] and [(ROPh)4PCu] were generated as crystals or solids. The 1H NMR, mass, FTIR, UV-Vis spectra and elemental analysis data were in good agreement with the assigned structures. The liquid crystalline (LC) properties of twenty compounds were studied by differential scanning calorimetry and polarizing microscope. It was observed that nineteen of them behaved as LC in a wide range of temperature. However, they displayed as heated monotropic liquid crystals.

Key words: meso-tetrakis(2-alkoxyphenyl)porphyrin, copper complex of porphyrin, synthesis, characterization, liquid crystal property