Acta Chimica Sinica ›› 2008, Vol. 66 ›› Issue (3): 385-390. Previous Articles     Next Articles

Original Articles

四磺基铁(II)酞菁生物模拟合成导电聚苯胺

胡兴*, 1,邹国林2,林敏1,赵庆1,李湘1   

  1. (1怀化学院生物工程系 怀化 418008)
    (2武汉大学生命科学学院 武汉 430072)
  • 收稿日期:2007-05-08 修回日期:2007-07-02 出版日期:2008-02-14 发布日期:2008-02-14
  • 通讯作者: 胡兴

Biomimetic Synthesis with Iron (II) Tetrasulfophthalocyanine of a Conducting Polyaniline

HU Xing*,1; ZOU Guo-Lin2; LIN Min1; ZHAO Qing1; LI Xiang1   

  1. (1 Department of Bioengineering, Huaihua University, Huaihua 418008)
    (2 College of Life Sciences, Wuhan University, Wuhan 430072)
  • Received:2007-05-08 Revised:2007-07-02 Online:2008-02-14 Published:2008-02-14
  • Contact: HU Xing

A new biomimetic route for the synthesis of a conducting polyaniline (PANI)/lignosulfonate (LGS) complex is presented. Iron (II) tetrasulfophthalocyanine (FeTSPc) is used to polymerize aniline in the presence of a natural polyelectrolytes template, LGS. The effects of pH, concentrations of aniline, LGS, H2O2, and reaction time on polymerization reaction of aniline were studied. The results show that the polymerization of aniline is strongly pH-dependent in this case. A wider range at low pH (1.0~4.0) was required to produce the conducting PANI. The optimal pH value is 1.5. UV–vis absorption, FTIR, elemental analysis, conductivity, cyclic voltammetry, and thermogravimetric analysis studies all confirm the thermally stable and reversible electroactive form of PANI complex.

Key words: iron (II) tetrasulfophthalocyanine, polyaniline, biomimetic, conductivity, lignosulfonate