Acta Chimica Sinica ›› 2011, Vol. 69 ›› Issue (09): 1029-1034.     Next Articles

Full Papers

微波合成Pt/WC催化剂及其对甲醇的电催化性能

施梅勤*,郎小玲,马淳安*,褚有群,陈赵扬,俞彬   

  1. (浙江工业大学化学工程与材料学院 绿色化学合成技术国家重点实验室培育基地
    科技部能源材料及应用国际科技合作基地 杭州 310032)
  • 收稿日期:2010-12-24 修回日期:2011-03-31 出版日期:2011-05-14 发布日期:2011-04-15
  • 通讯作者: 马淳安 E-mail:science@zjut.edu.cn
  • 基金资助:

    浙江省自然科学基金重点项目;浙江省重大科技专项国际合作项目;浙江省教育厅科研项目

Microwave Heated Synthesis of Pt/WC and Its Electrocatalytic Activity for Methanol Electrooxidation

SHI Mei-Qin, LANG Xiao-Ling, MA Chun-An, CHU You-Qun, CHEN Zhao-Yang, YU Bin   

  1. (State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, College of Chemical Engineering and Materials Science, Zhejiang University of Technology, International Sci. & Tech. Cooperation Base of Energy Materials and Application, Hangzhou 310032)
  • Received:2010-12-24 Revised:2011-03-31 Online:2011-05-14 Published:2011-04-15

Two types of Pt/WC catalysts were prepared by microwave-assisted (MW) polyol method and impregnation-reduction (IR) method. These catalysts were denoted as MW-Pt/WC and IR-Pt/WC respectively. The as prepared catalysts were characterized by using the techniques of XRD and SEM. The cyclic voltammogram (CV) of the methanol oxidation showed that MW-Pt/WC catalyst has the better performance than the IR-Pt/WC catalyst for methanol oxidation in terms of the onset potential and peak current. The chronoamperometry results demonstrated that the MW-Pt/WC yielded higher electrocatalytic activity comparing with IR-Pt/WC catalyst.

Key words: microwave, tungsten carbide, methanol oxidation, chronoamperometry

CLC Number: