Acta Chimica Sinica ›› 1983, Vol. 41 ›› Issue (1): 48-55. Previous Articles     Next Articles

Original Articles

气相色谱法研究配位化合物的热稳定性 II.草酸配位化合物的热分解动力学

汪信;吴沛成;忻新泉;戴安邦   

  1. 南京大学配位化学研究所
  • 出版日期:1983-01-15 发布日期:1983-01-15

Studies on thermal stabilities of coordination compounds by gas chromatography. ii. Kinetics of thermal decomposition of oxalato coordination compounds.

WANG XIN;WU PEICHENG;XIN XINQUAN;DAI ANBANG   

  • Online:1983-01-15 Published:1983-01-15

In this paper kinetics of thermal decomposition of oxalato coordination is stuided by gas chromatography. A kinetic equation of thermal decomposition is proposed. A computer program which was written in FORTRAN-IV language has been worked out to evaluate the activation energy and the Arrhenius pre-exponential factor. The results of calculation show that the equation is better agreement with the experimantal data. The activation step in decomposition of Fe(C2H4)3 is discussed on basis of calculation by EHMO method.

Key words: GAS CHROMATOGRAPHY, COMPLEX COMPOUNDS, THERMAL STABILITY, KINETICS EQUATIONS, OXALATO COMPLEX, THERMAL DECOMPOSITION

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