Acta Chimica Sinica ›› 2012, Vol. 70 ›› Issue (12): 1385-1393.DOI: 10.6023/A1201061 Previous Articles     Next Articles

Special Topic

二酰胺大环化合物与吡啶N-氧化物的络合作用研究

杨登科a, 曾志坚b, 陈木娟a, 潘绍武a, 杨宇a, 李媚a, 雷春燕a, 蒋腊生a   

  1. a 华南师范大学化学与环境学院 广州 510006;
    b 华南师范大学实验中心 广州 510006
  • 收稿日期:2012-01-06 修回日期:2012-03-20 出版日期:2012-06-28 发布日期:2012-03-29
  • 通讯作者: 蒋腊生 E-mail:jiang6128@yahoo.com.cn
  • 基金资助:

    国家自然科学基金(No. 21072066)资助项目.

Studies on the Complexation of di-Amide Based Macrocycles with Pyridine N-oxides

Yang Dengkea, Zeng Zhijianb, Chen Mujuana, Pan Shaowua, Yang Yua, Li Meia, Lei Chunyana, Jiang Lashenga   

  1. a School of Chemistry and Environment, South China Normal University, Guangzhou 510006;
    b Research Resources Centre, South China Normal University, Guangzhou 510006
  • Received:2012-01-06 Revised:2012-03-20 Online:2012-06-28 Published:2012-03-29
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21072066).

A new cationic host molecule was synthesized by reaction of the di-amide based macrocycle with methyl iodide and the structure was confirmed by NMR, ESI-MS spectra. The complexation behavior of the di-amide based macrocycles with pyridine N-oxide guests was investigated by means of ESI-MS and 1H NMR. The results showed that the cationic host can not only bind the pyridine N-oxide hosts to form 1∶ 1 pseudorotaxane-like complexes but also have much stronger binding ability than the corresponding neutral hosts.

Key words: macrocycles, host-guest chemistry, complexation, pseudorotaxane