Acta Chimica Sinica ›› 1982, Vol. 40 ›› Issue (12): 1123-1128. Previous Articles     Next Articles

吐鲁番风化煤黄腐酸的结构研究Ⅱ.

张德和, 刘登良, 张文信, 王光辉   

  1. 中国科学院化学研究所 北京
  • 收稿日期:1981-11-09 出版日期:1982-12-15 发布日期:2013-06-03
  • 通讯作者: 张德和

STUDY ON THE STRUCTURE OF FULVIC ACID FROM WEATHERED COAL OF TULUFAN Ⅱ.

ZHANG DE-HE, LIU DENG-LIANG, ZHANG WEN-XIN, WANG GUANG-HUI   

  1. Institute of Chemistry Academia Sinica, Beijing
  • Received:1981-11-09 Online:1982-12-15 Published:2013-06-03

Fulvia acid extracted from weathered coal (Tnlnfan, Xinjiang) was methylated with CH2N2 and was then fractionated.The higher molecular weight fractions G6-G12(M-663-6601) were oxidatively degraded.with KMnO4, The degradation products thus obtained were again methylatsd and were then separated into 24 components by G0, 17 of which were identified as the same compounds which had been separated from the low molecular weight fractions as reported previously.The other identified compounds are 1, 2, 3-benzene-trioarboxylic acid, 1, 2, 3, 4-benzene-tetraoarbogylio acid, isophthalia acid, terephthalio said, as well as a small amount of n-G18H38, G19H38 and 10-methyl-nonadecanoio acid.Differing from fulvio and humio acids from other origins, the fulvia acid now studied.has very remarkable aromatic struatural characteristics.