Acta Chim. Sinica ›› 2015, Vol. 73 ›› Issue (4): 307-309.DOI: 10.6023/A14120828 Previous Articles     Next Articles

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金属催化有机反应中的碱效应

秦国萍, 崔春明   

  1. 南开大学元素有机化学国家重点实验室 天津 300071
  • 投稿日期:2014-12-01 发布日期:2015-01-08
  • 通讯作者: 崔春明 E-mail:cmcui@nankai.edu.cn
  • 基金资助:

    项目受国家自然科学基金(No. 21172116)资助.

Base Effects in Metal-Catalyzed Organic Reactions

Qin Guoping, Cui Chunming   

  1. State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071
  • Received:2014-12-01 Published:2015-01-08
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21172116).

Organic and inorganic bases have been widely employed in many metal-catalyzed organic reactions to promote the catalytic efficiency and improve the selectivity. In many cases, a certain base only works well for one type of reactions and roles of the base cannot be clearly understood at present. Professor Xi's group at Peking University recently summarized the roles of bases in many catalytic transformations and discussed the possible factors of bases on these transformations. This is the first review article on the systematic analysis of the base effects. This highlight, based on this review and the related references, will briefly discuss base effects on catalytic organic transformations.

Key words: base effects, organic bases, inorganic bases, metal-catalyzed organic reactions