Acta Chim. Sinica ›› 2019, Vol. 77 ›› Issue (8): 681-689.DOI: 10.6023/A19040118 Previous Articles     Next Articles

Perspectives

共价有机框架在能源存储及转化中的研究进展

彭正康, 丁慧敏, 陈如凡, 高超, 汪成   

  1. 武汉大学分子与科学学院 武汉 430072
  • 收稿日期:2019-04-07 出版日期:2019-08-15 发布日期:2019-05-21
  • 通讯作者: 汪成 E-mail:chengwang@whu.edu.cn
  • 作者简介:彭正康,本科毕业于北京化工大学,现为武汉大学化学与分子科学硕士生,目前研究方向为共价有机框架的构筑及其电化学性质的探究;汪成,2003年获武汉大学学士学位,2008年在中国科学院化学研究所获理学博士学位,随后在美国西北大学化学系进行博士后研究.2012年4月加入武汉大学化学与分子科学学院,任教授、博士生导师.2013年被聘为湖北省"楚天学者"特聘教授,2015年获得湖北省杰出青年基金资助,2019年入选第四批"万人计划"青年拔尖人才.主要从事多孔框架晶体材料(包括COFs和MOFs)的研究.
  • 基金资助:

    项目受国家自然科学基金(No.21572170)资助.

Research Progress in Covalent Organic Frameworks for Energy Storage and Conversion

Peng Zhengkang, Ding Huimin, Chen Rufan, Gao Chao, Wang Cheng   

  1. College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072
  • Received:2019-04-07 Online:2019-08-15 Published:2019-05-21
  • Contact: 10.6023/A19040118 E-mail:chengwang@whu.edu.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21572170).

Covalent organic frameworks (COFs) are a class of porous crystalline materials consisting of organic units connected through covalent bonds. Due to their low density, high surface area and high thermal stability, COFs have found interesting applications in many fields, including molecular adsorption and separation, sensing, catalysis and optoelectronics devices. In particular, two-dimensional (2D) COFs have attracted increasing attention in energy fields. In this perspective, the applications of 2D COFs in energy storage (lithium ion batteries, lithium-sulfur batteries, supercapacitor and fuel cells) and energy conversion (water splitting and reduction of carbon dioxide) are reviewed. In addition, we will also discuss the remaining challenging issues.

Key words: covalent organic frameworks, rechargeable batteries, supercapacitor, fuel cells, water splitting, CO2 reduction