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     Acta Chimica Sinica, published monthly in Chinese by the Chinese Chemical Society since 1933 and originally named Journal of the Chinese Chemical Society before 1952, reports new research results in all fields of chemistry, including physical chemistry, inorganic chemistry, organic chemistry and analytic chemistry, etc., in the forms of accounts, articles, notes and communications. Accounts are summary of significant recent work and new developments from research groups of principal authors.
 
 
 
 
2019, 77(9)
   
 
 Content
    
      ,      2019, 77 (9), pp 0-0
     Publication Date(Web): (Content)
Abstract ( 41 )|Supporting Info
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2019年77卷09期封面及中英文目录


 Editorial
    Li Chaozhong, Zhu Chen
      ,      2019, 77 (9), pp 771-772
     Publication Date(Web): (Editorial)
     DOI:10.6023/A1909E001
Abstract ( 127 )|Supporting Info
PDF [640KB] ( 262 )
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 Perspectives
Radical-Type Difunctionalization of Alkenes with CO2
    Zhang Zhen, Gong Li, Zhou Xiao-Yu, Yan Si-Shun, Li Jing, Yu Da-Gang
      ,      2019, 77 (9), pp 783-793
     Publication Date(Web): 2019-07-12 (Perspectives)
     DOI:10.6023/A19060208
Abstract ( 102 )|Supporting Info
PDF [1194KB] ( 225 )
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二氧化碳参与的自由基型烯烃双官能团化反应


Visible Light Photoredox-Induced Smiles Rearrangement
    Chen Yilin, Chang Liang, Zuo Zhiwei
      ,      2019, 77 (9), pp 794-802
     Publication Date(Web): 2019-06-04 (Perspectives)
     DOI:10.6023/A19050179
Abstract ( 112 )|Supporting Info
PDF [1437KB] ( 168 )
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可见光催化诱导的Smiles重排研究进展


 Review
Application of Propargylic Radicals in Organic Synthesis
    Lu Fu-Dong, Jiang Xuan, Lu Liang-Qiu, Xiao Wen-Jing
      ,      2019, 77 (9), pp 803-813
     Publication Date(Web): 2019-08-13 (Review)
     DOI:10.6023/A19060201
Abstract ( 122 )|Supporting Info
PDF [1171KB] ( 232 )
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炔丙基自由基在有机合成化学中的应用


4-Substituted Hantzsch Esters as Alkylation Reagents in Organic Synthesis
    Ye Shengqing, Wu Jie
      ,      2019, 77 (9), pp 814-831
     Publication Date(Web): 2019-06-12 (Review)
     DOI:10.6023/A19050170
Abstract ( 147 )|Supporting Info
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4-取代的汉斯酯(Hantzsch Esters)作为烷基化试剂参与的有机反应


Advances on Transition Metals and Photoredox Cooperatively Catalyzed Allylic Substitutions
    Zhang Hong-Hao, Yu Shouyun
      ,      2019, 77 (9), pp 832-840
     Publication Date(Web): 2019-07-16 (Review)
     DOI:10.6023/A19050177
Abstract ( 102 )|Supporting Info
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过渡金属与光氧化还原协同催化的烯丙基取代反应的研究进展


Visible-Light-Induced N-Radical Directed Remote Functionalization of sp3 C-H Bonds
    Xiao Li, Li Jiaheng, Wang Ting
      ,      2019, 77 (9), pp 841-849
     Publication Date(Web): 2019-08-14 (Review)
     DOI:10.6023/A19050183
Abstract ( 46 )|Supporting Info
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可见光催化的氮自由基导向远程sp<sup>3</sup>碳氢官能团化反应


 Communication
Photoredox Catalysis for the Coupling Reaction of Nitrones with Aromatic Tertiary Amines
    Liu Yu-Cheng, Zheng Xiao, Huang Pei-Qiang
      ,      2019, 77 (9), pp 850-855
     Publication Date(Web): 2019-05-22 (Communication)
     DOI:10.6023/A19040150
Abstract ( 55 )|Supporting Info
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光催化氧化还原体系中硝酮与芳香叔胺的自由基偶联反应


Enantioselective Cyanation of Remote C-H Bonds via Cooperative Photoredox and Copper Catalysis
    Cheng Zhongming, Chen Pinhong, Liu Guosheng
      ,      2019, 77 (9), pp 856-860
     Publication Date(Web): 2019-08-15 (Communication)
     DOI:10.6023/A19070252
Abstract ( 190 )|Supporting Info
PDF [583KB] ( 208 )
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光/铜共催化远程C—H键的不对称氰基化反应


Activation of S-H and N-H Bonds to Synthesize Sulfinamides via Cross Coupling Hydrogen Evolution
    Liu Wen-Qiang, Yang Xiu-Long, Tung Chen-Ho, Wu Li-Zhu
      ,      2019, 77 (9), pp 861-865
     Publication Date(Web): 2019-04-22 (Communication)
     DOI:10.6023/A19030077
Abstract ( 80 )|Supporting Info
PDF [615KB] ( 108 )
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S—H键和N—H键交叉偶联放氢制备亚磺酰胺


Palladium-Catalyzed ortho-Selective C-H Chlorination of Arenes Using#br# Anodic Oxidation
    Yang Qi-Liang, Wang Xiang-Yang, Weng Xin-Jun, Yang Xiang, Xu Xue-Tao, Tong Xiaofeng, Fang Ping, Wu Xin-Yan, Mei Tian-Sheng
      ,      2019, 77 (9), pp 866-873
     Publication Date(Web): 2019-05-08 (Communication)
     DOI:10.6023/A19040135
Abstract ( 65 )|Supporting Info
PDF [692KB] ( 85 )
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电氧化促进的钯催化的芳烃C(sp<sup>2</sup>)—H键氯代反应


adical-Promoted Cross Dehydrogenative Coupling of Ketones and Esters with Electron-Rich Heteroarenes
    Xiao Yingxia, Liu Zhong-Quan
      ,      2019, 77 (9), pp 874-878
     Publication Date(Web): 2019-06-21 (Communication)
     DOI:10.6023/A19050189
Abstract ( 40 )|Supporting Info
PDF [530KB] ( 72 )
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富电子杂环芳烃与酮酯的自由基脱氢偶联反应


Modular Synthesis of Functionalized 4-Quinolones via a Radical Cyclization Cascade Reaction
    Qian Xiangyang, Xiong Peng, Xu Hai-Chao
      ,      2019, 77 (9), pp 879-883
     Publication Date(Web): 2019-07-01 (Communication)
     DOI:10.6023/A19050193
Abstract ( 51 )|Supporting Info
PDF [519KB] ( 58 )
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通过自由基串联环化反应合成4-喹诺酮类化合物


Copper-catalyzed Intramolecular Aminoperfluoroalkylation Reaction of O-Homoallyl Benzimidates
    Zhang Heng, Mou Xueqing, Chen Gong, He Gang
      ,      2019, 77 (9), pp 884-888
     Publication Date(Web): 2019-08-13 (Communication)
     DOI:10.6023/A19060220
Abstract ( 47 )|Supporting Info
PDF [518KB] ( 82 )
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铜催化苯甲酰亚胺高烯丙酯的分子内胺化全氟烷基化反应


Lewis Base-Boryl Radical Enabled Giese Reaction and Barton Decarboxylation of N-Hydroxyphthalimide (NHPI) Esters
    Jin Jikang, Zhang Fenglian, Wang Yifeng
      ,      2019, 77 (9), pp 889-894
     Publication Date(Web): 2019-07-09 (Communication)
     DOI:10.6023/A19050173
Abstract ( 39 )|Supporting Info
PDF [596KB] ( 86 )
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路易斯碱-硼自由基促进的邻苯二甲酰亚胺类羧酸酯的Giese反应和Barton脱羧反应研究


isible Light Promoted Ketoalkylation of Quinoxaline-2(1H)-ones via Oxidative Ring-Opening of Cycloalkanols
    Hai Man, Guo Li-Na, Wang Le, Duan Xin-Hua
      ,      2019, 77 (9), pp 895-900
     Publication Date(Web): 2019-05-21 (Communication)
     DOI:10.6023/A19040155
Abstract ( 41 )|Supporting Info
PDF [576KB] ( 76 )
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可见光促进环烷醇氧化开环的喹喔啉酮烷基化反应


Visible-Light Photocatalytic Remote Thiolation of Aldehydes Triggered by Sulfonylation of Alkenes With Thiosulfonates
    Yang Junhang, Fu Xiaobo, Lu Zenghui, Zh Gangguo
      ,      2019, 77 (9), pp 901-905
     Publication Date(Web): 2019-06-13 (Communication)
     DOI:10.6023/A19050161
Abstract ( 40 )|Supporting Info
PDF [579KB] ( 77 )
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可见光催化烯烃砜基化启动的远程醛基碳-氢键直接硫化反应


Copper-catalyzed ortho C-H Azidation of Anilines Using Molecular Oxygen as Terminal Oxidant
    Lin Fengguirong, Liang Yujie, Li Xinyao, Song Song, Jiao Ning
      ,      2019, 77 (9), pp 906-910
     Publication Date(Web): 2019-03-22 (Communication)
     DOI:10.6023/A19020070
Abstract ( 61 )|Supporting Info
PDF [584KB] ( 98 )
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氧气氧化铜催化的苯胺邻位叠氮化反应


Visible-Light-Driven Difluoroalkylation of Aromatics Catalyzed by Copper
    Dai Jianling, Lei Wenlong, Liu Qiang
      ,      2019, 77 (9), pp 911-915
     Publication Date(Web): 2019-08-14 (Communication)
     DOI:10.6023/A19050181
Abstract ( 21 )|Supporting Info
PDF [701KB] ( 60 )
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可见光驱使铜盐催化芳香烃二氟烷基化反应


ynthesis of β,γ-Unsaturated Esters and γ-Ketone Esters with Amino Acid Ester-Derived Katritzky Salts
    Zhao Yong, Li Shihong, Zhang Miaomiao, Liu Feng
      ,      2019, 77 (9), pp 916-921
     Publication Date(Web): 2019-05-22 (Communication)
     DOI:10.6023/A19040121
Abstract ( 67 )|Supporting Info
PDF [566KB] ( 82 )
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氨基酸酯Katritzky盐用于<em>β</em>,<em>γ</em>-不饱和酯和<em>γ</em>-酮酯合成的研究


 Article
Sulfonyl Chlorides Mediated Alkynylation of Non-activated Alkenes via Distal Alkynyl Group Migration
    Tang Nana, Shao Xin, Wang Mingyang, Wu Xinxin, Zhu Chen
      ,      2019, 77 (9), pp 922-926
     Publication Date(Web): 2019-06-04 (Article)
     DOI:10.6023/A19050158
Abstract ( 65 )|Supporting Info
PDF [559KB] ( 108 )
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磺酰氯参与的基于远端炔基迁移的非活化烯烃炔基化反应


Hydrogen Radical Initiated 1,2-Alkynyl Migration
    Zhao Qi, Tu Shu-Jiang, Jiang Bo
      ,      2019, 77 (9), pp 927-931
     Publication Date(Web): 2019-06-21 (Article)
     DOI:10.6023/A19040151
Abstract ( 135 )|Supporting Info
PDF [644KB] ( 134 )
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氢自由基引发的1,2-炔基迁移


Radical Promoted Annulation of Alkynones for the Construction of 2,3-Disubstituted Thiochromones
    Xu Jian, Zhang Shifan, Luo Ying, Zhang Li, Zhang Fan, Huang Tingjing, Song Qiuling
      ,      2019, 77 (9), pp 932-938
     Publication Date(Web): 2019-08-12 (Article)
     DOI:10.6023/A19050169
Abstract ( 42 )|Supporting Info
PDF [574KB] ( 89 )
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自由基促进硫甲基取代的炔酮的环化反应


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