有机化学 ›› 2012, Vol. 32 ›› Issue (04): 770-775.DOI: 10.6023/cjoc1109291 上一篇    下一篇

研究简报

新型不对称酞菁锌的合成和表征

俞孝伟a,b, 詹传郎b, 黄彦a   

  1. a 南京工业大学化学化工学院 材料化学工程国家重点实验室 南京 210009;
    b 中国科学院化学研究所 北京分子科学国家实验室 中国科学院光化学重点实验室 北京 100190
  • 收稿日期:2011-09-29 修回日期:2011-11-25 出版日期:2012-04-25 发布日期:2012-04-24
  • 通讯作者: 黄彦 E-mail:huangy@njut.edu.cn
  • 基金资助:

    国家自然科学基金(No. 20973182)资助项目.

Synthesis and Characterization of New Asymmetrical Phthalocyanine Zinc

Yu Xiaoweia,b, Zhan Chuanlangb, Huang Yana   

  1. a State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009;
    b Beijing National Laboratory for Molecular Sciences (BNLMS), Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190
  • Received:2011-09-29 Revised:2011-11-25 Online:2012-04-25 Published:2012-04-24
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 20973182).

以4-硝基邻苯二甲腈为主要原料, 合成了2(3),9(10),16(17),23(24)-四-(正庚酰胺基)-酞菁锌、2(3),9(10),16(17),23(24)-四-(甲氧基)-酞菁锌、2(3),9(10),16(17),23(24)-四-(对叔丁基苯氧基)-酞菁锌和2(3),9(10),16(17),23(24)-四-(苯氧基)-酞菁锌等4 种对称型酞菁. 在此基础上, 选取4-对叔丁基苯氧基邻苯二甲腈为前驱体, 采用概率法合成了含有氨基、羧基的2 种不对称酞菁锌(A3B).

关键词: 锌酞菁, 不对称酞菁, 合成, 前驱体, 概率法

Four kinds of symmetrical phthalocyanine zincs (PCZn) 2(3),9(10),16(17),23(24)-(tetraheptanylcarbonyl amino)-phthalocyanine zinc, 2(3),9(10),16(17),23(24)-tetramethoxy-phthalocyanine zinc, 2(3),9(10),16(17),23(24)-tetra-(4- tert-butylphenoxyl)-phthalocyanine zinc, and 2(3),9(10),16(17),23(24)-tetraphenoxyl-phthalocyanine zinc were synthesized from 4-nitro-phthalonitrile. Moreover, the 4-(4-tert-butylphenoxyl)phthalonitrile was employed as a precursor in the synthesis of two kinds of asymmetrical PCZn (A3B) containing either amino- or carboxyl-group by probability method.

Key words: phthalocyanine zinc, asymmetrical phthalocyanine, synthesis, precursor, probability method