有机化学 ›› 2014, Vol. 34 ›› Issue (11): 2236-2248.DOI: 10.6023/cjoc201403066 上一篇    下一篇

综述与进展

氟硼二吡咯亚甲基类荧光探针在离子检测中的应用进展

何源, 冯若昆, 易云瑞, 刘占祥   

  1. 浙江大学化学系 杭州 310007
  • 收稿日期:2014-03-30 修回日期:2014-06-13 出版日期:2014-11-25 发布日期:2014-07-01
  • 通讯作者: 刘占祥,liuzhanx@zju.edu.cn E-mail:liuzhanx@zju.edu.cn
  • 基金资助:

    国家自然科学基金(No.20802068)、浙江省自然科学基金(No.Y4110100)资助项目.

Recent Progress in the Research of Borondipyrromethene-Based Fluorescent Ion Chemosensor

He Yuan, Feng Ruokun, Yi Yunrui, Liu Zhanxiang   

  1. Department of Chemistry, Zhejiang University, Hangzhou 310007
  • Received:2014-03-30 Revised:2014-06-13 Online:2014-11-25 Published:2014-07-01
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No.20802068) and the Natural Science Foundation of Zhejiang Province (No.Y4110100).

氟硼二吡咯亚甲基类(BODIPY)类化合物具有摩尔吸光系数高、荧光量子产率高、吸收波长在可见光或近红外区域、荧光寿命长和光稳定性好等特点, 并且其荧光对溶剂的极性和pH均不敏感, 是一类可应用于生物领域的荧光染料, 近年来, 此类化合物被广泛用于设计合成荧光传感器分子, 用于各种离子的检测, 此类荧光探针具有分析灵敏度高、选择性好等特点. 综述了氟硼二吡咯亚甲基类荧光探针在离子识别和检测中的应用, 并展望了该领域的前景.

关键词: 氟硼二吡咯亚甲基(BODIPY), 荧光传感器, 选择性识别, 离子探针

Borondipyrromethene (BODIPY) derivatives have been widely exploited and recognized as useful fluorescent sensing and labeling reagents in biomolecules due to their unique photophysical properties, such as strong absorption in the visible and near-IR ranges, high fluorescence quantum yield and excellent photo-stability. Recently, many BODIPY-derived probes have been developed for the detection of metal ions. BODIPY dye as a kind of fluorescent probe has been obtained much attention, which has outstanding physicochemical properties and excerlent selectivity, and sentiivity. In this review, the progress in the fields of ion chemosensor based on BODIPY is summarized.

Key words: borondipyrromethene (BODIPY), fluorescent sensor, selective recognition, ion chemosensor