有机化学 ›› 2016, Vol. 36 ›› Issue (1): 72-82.DOI: 10.6023/cjoc201507015 上一篇    下一篇

综述与进展

低价(正一价)镁金属化合物的合成及其应用研究进展

马猛涛a, 王未凡a, 姚薇薇b   

  1. a 南京林业大学理学院 南京 210037
    b 南京中医药大学药学院 南京 210023
  • 收稿日期:2015-07-16 修回日期:2015-09-12 出版日期:2016-01-25 发布日期:2015-09-17
  • 通讯作者: 马猛涛, 姚薇薇 E-mail:mengtao@njfu.edu.cn;yww0715@hotmail.com
  • 基金资助:

    国家自然科学基金(No. 21372117)、江苏省自然科学基金(Nos. BK20141468, BK20130952)和江苏省“青蓝工程”资助项目.

Synthesis of Magnesium(I) Complexes and Their Applications

Ma Mengtaoa, Wang Weifana, Yao Weiweib   

  1. a College of Science, Nanjing Forestry University, Nanjing 210037;
    b College of Pharmacy, Nanjing University of Chinese Medicine, Nanjing 210023
  • Received:2015-07-16 Revised:2015-09-12 Online:2016-01-25 Published:2015-09-17
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21372117), the Natural Science Foundation of Jiangsu Province (Nos. BK20141468, BK20130952) and the Qing Lan Project of Jiangsu Province.

第二主族的碱土金属价态通常为0价和+2价. 2007年, 室温条件下稳定的一价镁金属化合物首次被成功合成, 随后一系列不同有机配体稳定的一价镁化合物陆续被制备, 它们已被证实在有机反应和无机反应中可作为可溶的、化学计量可控的、具有选择性的和安全的还原剂替代一些传统的还原剂. 主要介绍迄今为止室温稳定的一价镁金属化合物的制备方法以及其在无机、有机化学等方面的应用的最新进展.

关键词: 金属-金属键, 一价, 镁金属, 合成, 应用

The valence of the alkaline-earth metals (group 2 metals) usually is 0 and +2. In 2007, the first room temperature stable magnesium(I) complexes were synthesized. Subsequently a series of different organic ligands stablized Mg(I) complexes have been prepared. They can be used as hydrocarbon soluble, stoichiometric, selective, and safe reducing agents in organic and inorganic reactions to replace some traditional reductants. In this review the synthesis of room temperature stable magnesium(I) complexes and their applications in organic and inorganic chemistry are briefly introduced.

Key words: metal-metal bond, univalence, magnesium, synthesis, applications