有机化学 ›› 2017, Vol. 37 ›› Issue (7): 1667-1680.DOI: 10.6023/cjoc201702009 上一篇    下一篇

所属专题: 热点论文合辑

综述与进展

无过渡金属催化的C(sp2)-H键官能化反应构建C(sp2)-S键研究进展

刘云云, 熊进, 韦丽   

  1. 江西师范大学化学化工学院 南昌 330022
  • 收稿日期:2017-02-09 修回日期:2017-03-16 发布日期:2017-04-01
  • 通讯作者: 刘云云 E-mail:chemliuyunyun@jxnu.edu.cn
  • 基金资助:

    国家自然科学基金(No.21562024)资助项目.

Recent Advances in the C(sp2)-S Bond Formation Reactions by Transition Metal-Free C(sp2)-H Functionalization

Liu Yunyun, Xiong Jin, Wei Li   

  1. College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022
  • Received:2017-02-09 Revised:2017-03-16 Published:2017-04-01
  • Contact: 10.6023/cjoc201702009 E-mail:chemliuyunyun@jxnu.edu.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No.21562024).

含有C(sp2)-S键的芳基/烯基硫醚类化合物广泛存在于具有生物活性或其它潜在应用价值的有机化合物中.在过去的十来年时间,构建C(sp2)-S键的相关研究发展迅猛,大量新型高效的催化体系和丰富多样的反应底物被开发报道,极大地丰富了含有C(sp2)-S骨架的化合物合成的研究方法学.综述了2001~2016年期间通过无过渡金属催化的碳-氢键官能化反应构建C(sp2)-S键的研究进展.

关键词: 无过渡金属, C (sp2)-H键, 芳(杂)环, 烯基, C(sp2)-S键构建

Aryl/vinyl thioethers containing C(sp2)-S bonds are prevalent in biologically relevant molecules and compounds with other potential applications. Around the past decade, rapid progress has taken place in the research area of C(sp2)-S construction, and a large number of efficient new catalytic systems as well as structurally versatile substrates have been identified for such reactions, which significantly enriched the content of the synthetic methodologies on C(sp2)-S bond formation. This review introduces mainly the research advances on transition metal-free C(sp2)-S bond forming reaction by means of C(sp2)-H bond functionalization over the period of 2001~2016.

Key words: transition metal-free, C(sp2)-H bond, (Hetero)aryl, vinyl, C(sp2)-S bond formation