有机化学 ›› 2018, Vol. 38 ›› Issue (4): 812-824.DOI: 10.6023/cjoc201708019 上一篇    下一篇

综述与进展

Pd催化下烯烃、炔烃及芳烃的氧化偶联反应研究进展

徐利革, 黄亿, 刘炳艮, 牛云宏, 火星   

  1. 兰州大学化学化工学院 兰州 730000
  • 收稿日期:2017-08-09 修回日期:2017-09-18 出版日期:2018-04-24 发布日期:2017-10-24
  • 通讯作者: 火星 E-mail:huox@lzu.edu.cn
  • 基金资助:

    国家自然科学基金青年基金(No.21202068)资助项目.

Progress in Oxidative Coupling Reaction of Olefins, Alkynes and Aromatic Hydrocarbons Catalyzed by Palladium

Xu Lige, Huang Yi, Liu Binggen, Niu Yunhong, Huo Xing   

  1. College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000
  • Received:2017-08-09 Revised:2017-09-18 Online:2018-04-24 Published:2017-10-24
  • Contact: 10.6023/cjoc201708019 E-mail:huox@lzu.edu.cn
  • Supported by:

    Project supported by the National Science Foundation for Young Scientists of China (No. 21202068).

1967年,Fujiwara和Moritani首次报道了一种新型的交叉偶联反应,该反应是在过渡金属通常是钯的作用下芳基碳氢键直接偶联到烯烃碳氢键上,生成新的碳碳键.在接下来的几十年时间里,钯催化的氧化偶联反应成为了一种重要的有机合成手段,在相关领域已经涌现出很多令人瞩目的科研成果.综述了Pd催化下烯烃、炔烃及芳烃的氧化偶联反应研究进展.

关键词: 钯, 氧化偶联, 芳基烯烃, 烯烃

In 1967, Fujiwara and Moritani reported a type of cross coupling reaction where an aromatic C-H bond is directly coupled to an olefinic C-H bond, generating a new C-C bond in the first time. This reaction is performed in the presence of a transition metal, and typically palladium. In the next few decades, palladium-catalyzed oxidative coupling reactions have become an important method in organic synthesis, and a lot of achievements in scientific research have emerged in the relevant areas. The progress in oxidative coupling reaction of olefins, alkynes and aromatic hydrocarbons catalyzed by palladium is reviewed.

Key words: palladium, oxidative coupling, aryl olefin, alkene