有机化学 ›› 2018, Vol. 38 ›› Issue (8): 1897-1906.DOI: 10.6023/cjoc201804035 上一篇    下一篇

所属专题: 有机光催化合辑

综述与进展

光诱导的糖类化合物的合成与修饰

叶辉a,c, 肖聪b, 陆良秋c   

  1. a 黄冈师范学院 催化材料制备及应用湖北省重点实验室 黄冈 438000;
    b Department of Chemistry, Georgia State University, Atlanta GA 30302-4098, USA;
    c 华中师范大学化学学院 农药与化学生物学教育部重点实验室 武汉 430079
  • 收稿日期:2018-04-18 修回日期:2018-05-12 发布日期:2018-05-17
  • 通讯作者: 陆良秋 E-mail:luliangqiu@mail.ccnu.edu.cn
  • 基金资助:

    湖北省自然科学基金(Nos.2015CFC818,2015CFA033)、黄冈师范学院培育基金(No.201615503)、黄冈师范学院博士基金(No.2015001703)资助项目.

Photo-Induced Carbohydrate Synthesis and Modification

Ye Huia,c, Xiao Congb, Lu Liangqiuc   

  1. a Hubei Key Laboratory for Processing and Application of Catalytic Materials, Huanggang Normal University, Huanggang 438000;
    b Department of Chemistry, Georgia State University, Atlanta GA 30302-4098, USA;
    c Key Laboratory of Pesticide & Chemical Biology Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079
  • Received:2018-04-18 Revised:2018-05-12 Published:2018-05-17
  • Contact: 10.6023/cjoc201804035 E-mail:luliangqiu@mail.ccnu.edu.cn
  • Supported by:

    Project supported by Natural Science Foundation of Hubei Province (Nos. 2015CFC818, 2015CFA033), the Cultivation Fund Project of Huanggang Normal University (No. 201615503) and the Doctoral Fund Project of Huanggang Normal University (No. 2015001703).

近年来光诱导的氧化还原催化反应在糖类化合物合成与修饰中取得重要进展.概述了该领域的最新成果,重点介绍光催化策略在O-糖苷化反应、C-糖苷化反应、糖类化合物的官能团修饰和硫醇-烯烃偶联反应等四个方面的应用.

关键词: 光氧化还原催化, 糖类化合物, 糖苷化反应, 官能团修饰

The synthesis of carbohydrates through photoredox catalysis has achieved a great process in the past decade. This review highlights the latest advances in this research area, including the photo-induced O-glycosylation and C-glycosylation, and the functional group modification and thiol-ene coupling reactions of carbohydrates.

Key words: photoredox catalysis, carbohydrate, glycosylation, functional group modification