有机化学 ›› 2019, Vol. 39 ›› Issue (6): 1583-1595.DOI: 10.6023/cjoc201812042 上一篇    下一篇

所属专题: 金属有机化学

综述与进展

无过渡金属参与下光诱导的偶联反应构建碳-杂键的研究进展

任林静, 冉茂刚, 何佳芯, 钱燕, 姚秋丽   

  1. 遵义医科大学药学院 遵义 563003
  • 收稿日期:2018-12-22 修回日期:2019-03-19 出版日期:2019-06-25 发布日期:2019-04-16
  • 通讯作者: 姚秋丽 E-mail:yao.qiuli@zmc.edu.cn
  • 基金资助:

    国家自然科学基金(Nos.21462056,21801261)、贵州省联合基金(No.[2014]7542)和遵义医科大学(Nos.20163715,F-627,18zy-003)资助项目.

Recent Advance in the Transition-Metal Free Coupling Reactions for the Construction of C-X Bonds Induced by Light

Ren Linjing, Ran Maogang, He Jiaxin, Qian Yan, Yao Qiuli   

  1. Department of Pharmacy, Zunyi Medical University, Zunyi 563003
  • Received:2018-12-22 Revised:2019-03-19 Online:2019-06-25 Published:2019-04-16
  • Contact: 10.6023/cjoc201812042 E-mail:yao.qiuli@zmc.edu.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21462056, 21801261), the Science and Technology Foundation of Guizhou Province (No.[2014]7542) and the Zunyi Medical University (Nos. 20163715, F-627, 18zy-003).

近年来在光照条件下无过渡金属参与的偶联反应受到了广泛的关注,这些反应为C-N/S/P等键的构建提供了重要的方法,也在医药、农业或材料化工等领域得到了广泛的应用.重点介绍了近五年来在无过渡金属参与下由有机光氧化还原催化剂或光敏剂诱导构建C-N/S/P等键的光氧化还原反应.

关键词: 光化学, 自由基反应, 无过渡金属参与, 交叉偶联, 绿色化学

Tremendous advance has been achieved for the transition-metal free coupling reactions induced by light these years, providing important strategies for the construction of C-N/S/P bonds, which was used frequently in the preparation of pharmaceutical drugs, agricultural products or materials and so on. In this review, the recent advance for the photo-induced coupling reactions for the construction of C-N/S/P bonds under transition-metal free conditions is reviewed.

Key words: photochemistry, radical reactions, transition-metal-free, cross-coupling, green chemistry