有机化学 ›› 2005, Vol. 25 ›› Issue (02): 147-151. 上一篇    下一篇

综述与进展

钯催化卤代芳烃Ullmann偶合反应

梁云,李金恒*   

  1. (湖南师范大学化学化工学院化学生物学与中药分析重点实验室 长沙 410081)
  • 收稿日期:2004-01-31 修回日期:2004-06-07 出版日期:2005-01-15 发布日期:2005-01-15
  • 通讯作者: 李金恒

Palladium-Catalyzed Ullmann-Type Coupling of Aryl Halides

  1. (Key Laboratory of Chemical Biology & Traditional Chinese Medicine Research, College of Chemistry and Chemical
    Engineering, Hunan Normal University, Changsha 410081)
  • Received:2004-01-31 Revised:2004-06-07 Online:2005-01-15 Published:2005-01-15

Ullmann偶合反应是有机合成中构建碳—碳键最重要的方法之一. 综述了钯催化卤代芳烃Ullmann偶合反应的研究进展, 其中包括钯催化还原Ullmann偶合反应和钯催化氧化Ullmann偶合反应等两部分.

关键词: Ullmann反应, 还原偶合, 氧化偶合, 钯, 卤代芳烃

Ullmann-type coupling reaction is one of the most important methods to construct C—C bonds in organic synthesis. Recent advances in the palladium-catalyzed Ullmann-type coupling of aryl halides including reductive coupling and oxidative coupling reactions have been reviewed.

Key words: oxidative coupling, aryl halide, reductive coupling, Ullmann reaction, palladium