有机化学 ›› 2008, Vol. 28 ›› Issue (01): 127-130. 上一篇    下一篇

研究简报

手性方酰化哒嗪胺及铜(II)配合物的荧光性研究

熊俊如*,向清祥,陈稼轩,张元勤   

  1. (乐山师范学院化学与生命科学系 乐山 614004)
  • 收稿日期:2006-11-21 修回日期:1900-01-01 出版日期:2008-01-23 发布日期:2008-01-23
  • 通讯作者: 熊俊如

Synthesis and Fluorescence of Chiral Pyridazine Amine of Squaic Acid and Its Copper Complex

XIONG Jun-Ru*, XIANG Qing-Xiang, CHEN Jia-Xuan, ZHANG Yuan-Qin   

  1. (Department of Chemistry and Life Science, Leshan Teachers College, Leshan 614004)
  • Received:2006-11-21 Revised:1900-01-01 Online:2008-01-23 Published:2008-01-23
  • Contact: XIONG Jun-Ru

以3-甲基-6-氯哒嗪和α-氨基丙醇、方酸为原料合成了一种新的手性方酰化哒嗪胺衍生物和铜(II)配合物, 新化合物和铜(II)配合物结构用IR, 1H NMR及元素分析对其表征. 并对新化合物的铜(II)配合物的荧光性进行了研究.

关键词: 手性方酰化氨基醇, 哒嗪衍生物, 铜配合物, 荧光性

A new chiral N-squaryl-N-(pyridazin-3-yl)-methyl-amine was synthesized from 3-methyl-6- chloropyridazine, alaninol and squarc acid and then its copper complex was prepared. The new compounds were confirmed by IR, 1H NMR spectra and elemental analysis. Fluorescence of the copper(II) complex was also studied.

Key words: pyridazine, chiral squaric acid amidoalcohol, copper(II) complex, fluorescence