有机化学 ›› 2005, Vol. 25 ›› Issue (09): 1029-1038. 上一篇    下一篇

综述与进展

三氯化铈促进的反应及其在有机合成中的应用

范学森*,1,李艳贞1,张永敏2,3   

  1. (1河南师范大学化学与环境科学学院 新乡 453007)
    (2浙江大学西溪校区化学系 杭州 310028)
    (3中国科学院上海有机化学研究所金属有机化学国家重点实验室 上海 200032)
  • 收稿日期:2004-10-25 修回日期:2005-02-28 发布日期:2005-08-24
  • 通讯作者: 范学森

Cerium(III) Chloride Promoted Reactions and Their Applications to Organic Synthesis

FAN Xue-Sen*,1,LI Yan-Zhen1,ZHANG Yong-Min2,3   

  1. (1 School of Chemical and Environmental Sciences, Henan Normal University, Xinxiang 453007)
    (2 Department of Chemistry, Zhejiang University at Xixi Campus, Hangzhou 310028)
    (3 State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry,
    Chinese Academy of Sciences, Shanghai 200032)
  • Received:2004-10-25 Revised:2005-02-28 Published:2005-08-24

综述了近年来三氯化铈促进的多种有机反应及其在有机合成中的应用, 其中重点讨论了三氯化铈促进下的碳—碳原子键、碳—杂原子键的形成反应以及多种保护基团的选择性脱保护反应等.

关键词: 三氯化铈, 路易斯酸, 有机反应, 有机合成

Recent progress in cerium(III) chloride promoted organic reactions and their applications to organic synthesis were reviewed in this paper with the focus on carbon-carbon and carbon-heteroatom bonds formation reactions and selective deprotection reactions.

Key words: organic reaction, organic synthesis, Lewis acid, cerium(III) chloride