有机化学 ›› 2014, Vol. 34 ›› Issue (1): 81-91.DOI: 10.6023/cjoc201307024 上一篇    下一篇

综述与进展

过渡金属催化端炔的氧化交叉偶联反应研究进展

张聪霞, 李娜娜, 李兴, 常宏宏, 刘强, 魏文珑   

  1. 太原理工大学 化学化工学院生物与制药工程系 太原 030024
  • 收稿日期:2013-07-20 修回日期:2013-09-03 出版日期:2014-01-25 发布日期:2013-09-17
  • 通讯作者: 魏文珑 E-mail:weiwenlong@tyut.edu.cn
  • 基金资助:

    山西省自然科学基金(Nos. 2012021007-2,2011011010-2)及山西省高等教育机构科技创新(No. 20120006)资助项目.

Progress in Transition-Metal-Catalyzed Oxidative Cross-Coupling of Terminal Alkynes

Zhang Congxia, Li Nana, Li Xing, Chang Honghong, Liu Qiang, Wei Wenlong   

  1. College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024
  • Received:2013-07-20 Revised:2013-09-03 Online:2014-01-25 Published:2013-09-17
  • Supported by:

    Project supported by the Natural Science Foundation of Shanxi Province (Nos. 2012021007-2, 2011011010-2), and the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi Province (No. 20120006).

炔基化合物是有机合成中重要的一类官能团化合物,端基炔通过氧化交叉偶联反应可以制备各种各样新的炔基化合物. 总结了近年来端基炔参与的氧化交叉偶联反应,主要介绍了Pd,Cu,Fe等过渡金属催化的端炔氧化交叉偶联反应研究进展.

关键词: 过渡金属, C—H键, 端基炔, 氧化交叉偶联, 进展

Alkynyl compounds are one kind of important functional compounds in organic synthesis. Various new alkynyl compounds can be obtained via oxidative cross-coupling reactions of terminal alkynes. Recent oxidative cross-coupling reactions involving terminal alkynes are reviewed. The advances of cross-coupling reactions catalyzed by Pd, Cu, Fe and so on are particularly described.

Key words: transition metal, C—H bond, terminal alkyne, oxidative cross-coupling, progress