有机化学 ›› 2014, Vol. 34 ›› Issue (1): 65-80.DOI: 10.6023/cjoc201307035 上一篇    下一篇

综述与进展

镍催化酚衍生物的Suzuki-Miyaura偶联反应研究进展

陈国军a, 杜建时b   

  1. a 长春工程学院理学院 长春 130012;
    b 吉林大学中日联谊医院血管外科 长春 130033
  • 收稿日期:2013-07-23 修回日期:2013-09-06 出版日期:2014-01-25 发布日期:2013-09-25
  • 通讯作者: 陈国军,杜建时 E-mail:chenguojun0082@163.com; dujianshi3043@126.com

Progress of Nickel-Catalyzed Suzuki-Miyaura Cross-Coupling Reactions of Phenol Derivatives

Chen Guojuna, Du Jianshib   

  1. a College of Science, Changchun Institute of Technology, Changchun 130012;
    b Vascular Surgery, The Third Hospital of Jilin University, Changchun 130033
  • Received:2013-07-23 Revised:2013-09-06 Online:2014-01-25 Published:2013-09-25

过渡金属镍催化的Suzuki-Miyaura偶联反应在有机合成中有着广泛的应用. 综述了近年来以过渡金属镍催化的以酚的衍生物为底物的偶联反应的研究进展. 主要包括芳基磺酸酯、氨基磺酸芳基酯、碳酸芳基酯、芳基羧酸酯、氨基甲酸芳基酯、芳基磷酸酯、芳醚、杂芳醚和酚盐的偶联反应.

关键词: 镍, 酚衍生物, Suzuki-Miyaura偶联反应

Suzuki-Miyaura coupling reaction catalyzed by transition-metal nickel is widely used in organic synthesis. In this review, the development of transition-metal nickel-catalyzed cross-coupling reactions is summarized, mainly including aryl sulfonates, aryl sulfamates, aryl carbonates, aryl carboxylates, aryl carbamates, aryl phosphorus derivatives, aryl ethers, aryl heteroaryl ethers and phenolate.

Key words: nickel, phenol derivatives, Suzuki-Miyaura cross-coupling reaction