有机化学 ›› 2015, Vol. 35 ›› Issue (2): 428-431.DOI: 10.6023/cjoc201409033 上一篇    下一篇

研究论文

光萼台中荚蒾叶中新二氧杂三环癸烷骨架环烯醚萜类化学成分的研究

杨国勋a, 叶淼b,c, 胡长玲a, 熊娟a, 胡金锋a,b   

  1. a 复旦大学药学院天然药物化学教研室 上海 201203;
    b 华东师范大学化学系 上海 200062;
    c 福建中医药大学药学院 福州 350122
  • 收稿日期:2014-09-20 修回日期:2014-10-15 出版日期:2015-02-25 发布日期:2014-10-22
  • 通讯作者: 胡金锋 E-mail:jfhu@fudan.edu.cn
  • 基金资助:

    国家自然科学基金(Nos. 21472021, 81273401, 81202420)、教育部高等学校博士学科点基金(Nos. 20120071110049, 20120071120049).

New Iridoids Possessing a Dioxatricyclodecane Skeleton from the Leaves of Viburnum formosanum Hayata subsp. leiogynum Hsu

Yang Guoxuna, Ye Miaob,c, Hu Changlinga, Xiong Juana, Hu Jinfenga,b   

  1. a Department of Natural Products Chemistry, School of Pharmacy, Fudan University, Shanghai 201203;
    b Department of Chemistry, East China Normal University, Shanghai 200062;
    c School of Pharmacy, Fujian University of Traditional Chinese Medicine, Fuzhou 350122
  • Received:2014-09-20 Revised:2014-10-15 Online:2015-02-25 Published:2014-10-22
  • Supported by:

    Project supported by the National Natural Science Foundation of Chin (Nos. 21472021, 81273401, 81202420), the Ph.D. Program Foundation of Ministry of Education (MOE) of China (Nos. 20120071110049, 20120071120049).

对光萼台中荚蒾(Viburnum formosanum Hayata subsp. leiogynum Hsu)的化学成分进行了研究, 从其叶子的EtOAc/MeOH (V:V=1:1)提取物中分离得到2个新的二氧杂三环癸烷结构骨架的环烯醚萜类化合物. 新化合物的化学结构及其相对立体构型通过综合波谱解析得到了确定.

关键词: 光萼台中荚蒾, 环烯醚萜, 二氧杂三环癸烷

The chemical constituents of Viburnum formosanum Hayata subsp. leiogynum Hsu have been studied for the first time. As a result, two new iridoids bearing a dioxatricyclodecane skeleton have been isolated and elucidated by extensive spectroscopic analysis from EtOAc/MeOH (V:V=1:1) extract of leaves of the title plant.

Key words: Viburnum formosanum Hayata subsp. leiogynum Hsu, iridoid, dioxatricyclodecane