有机化学 ›› 2015, Vol. 35 ›› Issue (4): 813-826.DOI: 10.6023/cjoc201409022 上一篇    下一篇

综述与进展

钯催化C—H乙酰氧基化反应

陈天保, 章明   

  1. 江西师范大学化学化工学院 南昌 330022
  • 收稿日期:2014-09-11 修回日期:2014-10-30 出版日期:2015-04-25 发布日期:2014-11-28
  • 通讯作者: 章明 E-mail:zmchem@163.com
  • 基金资助:

    国家自然科学基金(No. 21262017)资助项目.

Palladium-Catalyzed C—H Acetoxylation Reations

Chen Tianbao, Zhang Ming   

  1. College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022
  • Received:2014-09-11 Revised:2014-10-30 Online:2015-04-25 Published:2014-11-28
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21262017).

Pd催化的C—H官能化反应是目前有机合成方法学的一个重要研究热点. 毫无疑问, 这种温和又有选择性地转化方式广泛运用于化学各个领域. 钯催化反应在近十年内得到了很大的发展,但是对于有机化学家来说仍然是一个挑战. 综述了近十年来关于在C(sp2)—H和C(sp3)—H乙酰氧基化反应的研究进展及其应用, 并提出了今后的研究重点和发展趋势.

关键词: 钯, 催化, 乙酰氧基化

Palladium-catalyzed C—H functionalization is one of the hot topics in the field of organic synthesis methodology. Mild and selective transformation of this type will undoubtedly find widespread application across the chemistry. Even though Pd-catalyzed reaction has been deeply developed over past decades, it remains to be a huge challenge in organic chemistry. Herein, this review presents the recent progress for palladium-catalyzed C(sp2)—H and C(sp3)—H acetoxylation and their applications in the synthesis of complex molecules. Moreover, the research trend of this area is also prospected.

Key words: palladium, catalysis, acetoxylation