有机化学 ›› 2015, Vol. 35 ›› Issue (4): 802-812.DOI: 10.6023/cjoc201410012 上一篇    下一篇

综述与进展

有机硅试剂参与过渡金属催化的C—H官能团化反应形成C—C键的研究进展

罗海清, 张志鹏, 刘海东, 柳辉金   

  1. 赣南师范学院化学化工学院 赣州 341000
  • 收稿日期:2014-10-09 修回日期:2014-11-07 出版日期:2015-04-25 发布日期:2014-12-02
  • 通讯作者: 罗海清 E-mail:luohaiq@sina.com
  • 基金资助:

    江西省教育厅自然科学基金(Nos. GJJ14668, KJLD14080)及江西省普通本科高校中青年教师发展计划访问学者专项资金资助项目.

Advance of Organosilane in Transition-Metal-Catalyzed C—H Functionalization for C—C Bond Formation

Luo Haiqing, Zhang Zhipeng, Liu Haidong, Liu Huijin   

  1. Department of Chemistry & Chemical Engineering, Gannan Normal University, Ganzhou 341000
  • Received:2014-10-09 Revised:2014-11-07 Online:2015-04-25 Published:2014-12-02
  • Supported by:

    Project supported by the Natural Science Foundation of Jiangxi Provincial Education Department (Nos. GJJ14668, KJLD14080) and the Young Teacher Development Plan Visiting Scholar Special Funds of Jiangxi Ordinary Undergraduate Course Colleges and Universities.

作为一类重要的有机金属试剂, 有机硅试剂在有机合成化学的C—C键形成中得到了广泛应用. 综述了近年来有机硅试剂参与的过渡金属催化下C—H官能团化反应形成C—C键的研究进展, 重点介绍了Pd催化下C—H官能团化的Hiyama偶联反应.

关键词: 有机硅试剂, C—H官能团化, 过渡金属催化, C—C键形成, Hiyama偶联反应

As a kind of important organometallic reagents, organosilanes have been widely applied for C—C bond formation in organic synthesis. In this paper, recent development of trans-metal-catalyzed C—H functionalizations for C—C bond formation involving organosilanes is reviewed, in which Pd-catalyzed Hiyama coupling reactions is described as highlighted.

Key words: organosilane, C—H functionalizations, trans-metal catalyzed, C—C bond formation, Hiyama coupling reactions