有机化学 ›› 2017, Vol. 37 ›› Issue (1): 40-46.DOI: 10.6023/cjoc201607026 上一篇    下一篇

综述与进展

5-羟甲基糠醛加氢制备1-羟基-2,5-己二酮的研究进展

许占威, 颜佩芳, 张宗超   

  1. 中国科学院大连化学物理研究所 清洁能源国家实验室 催化基础国家重点实验室 大连 116023
  • 收稿日期:2016-07-18 修回日期:2016-08-22 出版日期:2017-01-25 发布日期:2016-09-06
  • 通讯作者: 张宗超 E-mail:zczhang@yahoo.com
  • 基金资助:

    中国博士后面上资助一等资助(No. 2013M540236)、中国科学院/国家外国专家局“创新团队国际合作伙伴计划”、国家千人计划资助项目.

Advance in the Hydrogenation of 5-Hydroxymethylfurfural to Produce 1-Hydroxyhexane-2,5-dione

Xu Zhanwei, Yan Peifang, Zhang Zongconrad   

  1. Dalian National Laboratory for Clean Energy, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023
  • Received:2016-07-18 Revised:2016-08-22 Online:2017-01-25 Published:2016-09-06
  • Supported by:

    Project supported by the China Postdoctoral Science Foundation(No. 2013M540236), the Chinese Academy of Sciences/State Administration of Foreign Experts Affairs International Partnership Program for Creative Research Teams, and the Chinese Government "Thousand Talent" Program Funding.

生物质基平台化合物5-羟甲基糠醛的转化研究是近年来的研究热点之一,1-羟基-2,5-己二酮是一种具有广泛应用前景的化合物.由5-羟甲基糠醛加氢制备1-羟基-2,5-己二酮是一种重要的合成策略,具有绿色、原子经济性高等优势,取得了一些重要的研究进展.从非均相催化和均相催化两方面对1-羟基-2,5-己二酮的制备进行了综述,讨论了催化体系的优劣和催化机理的研究.

关键词: 生物质, 呋喃, 氢化作用,

Recently,catalytic transformation of biobased 5-hydroxymethylfurfural(5-HMF) has been paid much more attentions.1-Hydroxyhexane-2,5-dione(HHD) is a potential feedstock to synthesize valuable chemicals.The recent remarkable progress of HHD preparation,which utilized 5-HMF as a starting material,is a green and atom economic method.In this review,the approaches of HHD preparation from 5-HMF are summarized based on the homogeneous and heterogeneous catalysis.

Key words: biomass, furan, hydrogenation, ketones