有机化学 ›› 2019, Vol. 39 ›› Issue (5): 1293-1303.DOI: 10.6023/cjoc201810036 上一篇    下一篇

综述与进展

过渡金属催化有机钛试剂的偶联反应研究进展

黄辉, 李娟华, 刘昆明, 刘晋彪   

  1. 江西理工大学冶金与化学工程学院 赣州 341000
  • 收稿日期:2018-10-29 修回日期:2018-12-19 出版日期:2019-05-25 发布日期:2019-01-10
  • 通讯作者: 刘昆明, 刘晋彪 E-mail:liukunminglkm@sina.com;liujbgood@hotmail.com
  • 基金资助:

    国家自然科学基金(Nos.21762018、21772067)、江西省教育厅科技项目(No.GJJ160668)、江西理工大学清江青年英才计划项目、江西理工大学大学生创新创业训练计划项目(No.XZG-16-08-12)及江西理工大学博士启动经费资助项目.

Recent Progress in Transition Metal-Catalyzed Coupling Reactions of Organotitanium Reagents

Huang Hui, Li Juanhua, Liu Kunming, Liu Jinbiao   

  1. School of Metallurgical and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000
  • Received:2018-10-29 Revised:2018-12-19 Online:2019-05-25 Published:2019-01-10
  • Contact: 10.6023/cjoc201810036 E-mail:liukunminglkm@sina.com;liujbgood@hotmail.com
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21762018, 21772067), the Science and Technology Project Founded by the Education Department of Jiangxi Province (No. GJJ160668), the Program of Qingjiang Excellent Young Talents, Jiangxi University of Science and Technology, the Innovation and Entrepreneurship Training Program (No. XZG-16-08-12) and the Doctoral Scientific Research Foundation of Jiangxi University of Science and Technology.

有机钛试剂廉价低毒,形态多样,具有优异的化学、区域和立体选择性.通过调整中心钛原子的配体可对有机钛试剂的反应活性进行调控.近年来,有机钛试剂参与的偶联反应引起了化学家们的广泛关注.从有机钛试剂类型出发,就过渡金属催化有机钛试剂的偶联反应进行了简要综述.

关键词: 过渡金属, 催化, 有机钛试剂, 偶联

Organotitanium proves to be one of ideal organometallic candidates because of its low price, non-toxicity, diversified types, excellent chemo-, regio- and stereo-selectivities. The reactivity of organotitanium reagent could be easily controlled by ligands of central titanium atom. Recently, the coupling reactions of organotitanium reagent have attracted extensive attention. This review summerized recent progress in transiton metal-catalyzed coupling reactons of organotitanium reagents concerning their types.

Key words: transition metal, catalysis, organotitanium reagent, coupling