Chin. J. Org. Chem. ›› 2012, Vol. 32 ›› Issue (01): 30-45.DOI: 10.6023/cjoc1104221 Previous Articles     Next Articles



张华承, 刘召娜, 辛飞飞, 郝爱友   

  1. 山东大学化学与化工学院 济南 250100
  • 收稿日期:2011-04-22 修回日期:2011-07-01 发布日期:2011-07-14
  • 通讯作者: 郝爱友

Organic Synthesis Based on Cyclodextrins Template Method

Zhang Huacheng, Liu Zhaona, Xin Feifei, Hao Aiyou   

  1. School of Chemistry & Chemical Engineering, Shandong University, Jinan 250100
  • Received:2011-04-22 Revised:2011-07-01 Published:2011-07-14

The organic synthesis based on cyclodextrin template method is reviewed initially by using the “template” concept. These organic synthesis reactions are divided into two main types: one type is based on cyclodextrin “static” template which includes the primary, secondary faces and the cavity. The reactions based on the primary and secondary faces mainly show that the template can control the stereo-structure. While the reactions based on the cavity are mainly using the size and chiral properties of the cavity to do the chemical, regio- and stereo-selectivity, showing that the template can carry out information transfer. The other type is based on cyclodextrin “dynamic” template including the bridge-linked cyclodextrin dimmers with variable conformations and the assemblies prepared by the cyclodextrin derivatives and inclusion complexes. These dynamic templates themselves can be adjusted.

Key words: cyclodextrin, template method, organic synthesis, application, catalysis