Chin. J. Org. Chem. ›› 2013, Vol. 33 ›› Issue (04): 675-686.DOI: 10.6023/cjoc201301019 Previous Articles     Next Articles



夏晓峰, 李莲花, 梁永民   

  1. 兰州大学 功能有机分子化学国家重点实验室 兰州 730000
  • 收稿日期:2013-01-09 修回日期:2013-02-01 发布日期:2013-02-18
  • 通讯作者: 梁永民
  • 基金资助:

    国家自然科学基金(No. 21072080)资助项目.

Platinum-Catalyzed the Rearrangement of Propargylic Esters and C—H Bond Functionalization Adjacent to the Nitrogen of Tertiary Amines

Xia Xiaofeng, Li Lianhua, Liang Yongmin   

  1. State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000
  • Received:2013-01-09 Revised:2013-02-01 Published:2013-02-18
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21072080).

Our recent progress in platinum-catalyzed the rearrangement of propargylic esters and C—H bond functionalization adjacent to the nitrogen of tertiary amines is summaried. The effect of the design of the substrates and additives on these reactions is described, and the mechanisms of these reactions are also discussed. At the same time, the first oxidant-free cross-dehydrogenative coupling (CDC) reaction under platinum-catalysis is proposed.

Key words: platiunm-catalysis, oxidative dehydrogenation, tandem reaction, rearrangement