Chin. J. Org. Chem. ›› 2013, Vol. 33 ›› Issue (04): 738-748.DOI: 10.6023/cjoc201301081 Previous Articles     Next Articles



房华毅, 凌镇, 付雪峰   

  1. 北京大学化学与分子工程学院 北京 100871
  • 收稿日期:2013-01-31 修回日期:2013-03-14 发布日期:2013-03-15
  • 通讯作者: 付雪峰

N—H Bond Activation of Ammonia by Transition Metal and Main Group Element Complexes

Fang Huayi, Ling Zhen, Fu Xuefeng   

  1. College of Chemistry and Molecular Engineering, Peking University, Beijing 100871
  • Received:2013-01-31 Revised:2013-03-14 Published:2013-03-15

Activation of ammonia has received increasing attention in recent years due to its important role both in nature and industry processes. A series of transition metal (such as Ir, Rh, Ru, Fe, Pd, etc.) and main group element (such as Si, Ge, Sn, etc.) complexes have been reported to activate N—H bond of ammonia in the past three decades. This review includes the recent progresses in homogeneous N—H bond activation of ammonia by transition metal and main group element complexes.

Key words: Ammonia, N—H bond, activation , transition metal complex, main group element complex