Chin. J. Org. Chem. ›› 2013, Vol. 33 ›› Issue (12): 2504-2514.DOI: 10.6023/cjoc201306039 Previous Articles     Next Articles

Reviews

直接芳基化缩聚法制备共轭聚合物的研究进展

孙敏敏, 周铭露, 梁露英, 王维, 王文, 凌启淡   

  1. 福建省高分子材料重点实验室 福建师范大学材料科学与工程学院 福州 350007
  • 收稿日期:2013-06-28 修回日期:2013-07-27 出版日期:2013-12-25 发布日期:2013-08-16
  • 通讯作者: 凌启淡, 王文 E-mail:qdling@fjnu.edu.cn;polywangwen@yahoo.com.cn
  • 基金资助:

    国家自然科学基金(Nos. 60976019,61250016)和福建省教委A类项目(No. JA12069)资助项目.

Research Progress in Conjugated Polymer Prepared by Direct (Hetero) Arylation Polycondensation

Sun Minmin, Zhou Minglu, Liang Luying, Wang Wei, Wang Wen, Ling Qidan   

  1. Fujian Key Laboratory of Polymer Materials, College of Materials Science and Engineering, Fujian Normal University, Fuzhou 350007
  • Received:2013-06-28 Revised:2013-07-27 Online:2013-12-25 Published:2013-08-16
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 60976019, 61250016) and the Education Department Program of Fujian Province A Project (No. JA12069).

In recent years, polycondensation via direct arylation has become widely recognized as an atom-economic and environmentally friendly method to prepare π-conjugated polymers, which drawing lots of researchers attention. Comparing with traditional cross-coupling reactions, the direct arylation of polymerization has many advantages, such as fewer synthetic steps, less time, higher monomer purity, less harmful substances on human beings and the environment, etc. Herein, the latest progress in direct arylation polycondensation about preparing different types of conjugated polymers was summarized. At the same time, the reaction mechanism of some factors influence on direct arylation polycondensation reaction was explored, including the polymerizable monomer, the reaction time, solvent, etc. The suitable for direct arylation of polycondensation reaction monomer characteristics was gained by comparing the data of polymerization product.

Key words: direct (hetero) arylation polycondensation, conjugated polymers, catalytic system